Elastomag FE magnesium oxide is used as an acid acceptor in specialty elastomers and fluoroelastomers. Isophoronediamine (IPDA). except when a special product is requested or required. Accelerator for epoxy/polyamine and epoxy/polyamide systems. Pores in the vulcanizate can be avoided with it. The curing process can be monitored by measuring changes in various parameters: Ultrasonic cure monitoring methods are based on the relationships between changes in the characteristics of propagating ultrasound and the real-time mechanical properties of a component, by measuring: Gregory T. Carroll, Nicholas J. Turro and Jeffrey T. Koberstein (2010), Ullmann's Encyclopedia of Industrial Chemistry, https://en.wikipedia.org/w/index.php?title=Curing_(chemistry)&oldid=1130952935, the concentration of specific reactive resin species using. The stronger the molecular bonds are, the harder the material surface is. Cure monitoring is, for example, an essential component for the control of the manufacturing process of composite materials. Salicylic acid-free. For solventfree paints, self-leveling and trowelable floorings, mortars, patching compounds and adhesives. The needs of our customers will always come first. Raw Material The typical raw materials of UHPC include cement, silica fume, fine sand, water and superplasticizer as shown in Table 1. Excellent UV resistance, Urethane bis oxazolidine, 4 functional, single pack and 2k with lower odor, Reactive diluent and pot life retarder for 2k systems, improves thin film set, diluent for 1K. As mentioned previously they can be combined with other curing agents for use in an extensive number of other applications, included to reduce viscosity and/or extend pot-life. In the case of concrete, curing entails the formation of silicate crosslinks. Curing serves these main purposes: It retains moisture in the slab so that the concrete continues to gain strength. Alternative to Mannich bases. For solventfree self-leveling and trowelable floorings, mortars, patching compounds, adhesives and encapsulation systems. The curing agent gets absorbed by the reaction and is integrated into the film's three-dimensional structure, contributing to the . Question: what is the recommended curing agent for a 2-parts anhydrous epoxy system? Curing is a chemical process employed in polymer chemistry and process engineering that produces the toughening or hardening of a polymer material by cross-linking of polymer chains. Rubber compounds containing Perkadox 14-408-pd have excellent scorch safety, under certain conditions one step mixing is possible. Polydimethylsiloxane (PDMS) is a two-part polymer (Base Elastomer and Curing Agent). For solvenfree self-leveling and trowelable floorings, paints or adhesives. [7] With dynamic mechanical analysis, the storage modulus (G) and the loss modulus (G) can be measured. Gel time adjustable to < 1 minute to over 2 hours. QR Polymers provide curing agents for epoxy resins, mainly for applications at room temperature. f Good gloss retention. Grade 103 USPL offers ultra-low lead (the lowest lead attainable), with the lowest m2/g surface area (SA) available with discrete French Process. Outstanding corrosion protection when combined with solid resin. For solventfree paints, floorings, mortars or adhesives. Any cookies that may not be particularly necessary for the website to function and is used specifically to collect user personal data via analytics, ads, other embedded contents are termed as non-necessary cookies. All available from the same centralized U.S. shipping point. Epoxy resin is the most widely used raw material for formulating heat curing one component adhesives. When catalysts are activated by ultraviolet radiation, the process is called UV cure.[6]. The primary ingredient in paint hardener is sodium polyacrylate, which is a crystallized salt product. For solventborne anticorrosion paints. If youre ready to start curing, here are a few different processes worth considering. Martin Marietta Magnesia Specialties, LLC. Privacy Policy Benzyl alcohol-free. Contact ustoday for more product information or to request a quote. Hardeners can be mixed in any ratio to fine tune reactivity. Our product line is one of the most comprehensive offerings of epoxy and polyurethane intermediates produced in North America. d What is claimed is: 1. Trigonox 17-40B-pd-am is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Terms & Conditions Trigonox C is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. required. [8]. The possibilities of polymer systems based on aliphatic-amine curing agents were systematically investigated last century, and the use of cycloaliphatic amines allows one to obtain adhesives, compounds, and matrices for composite materials with improved technological and operational characteristics [5, 6]. O VOC. General purpose high-solids curing agent for heavy duty coatings. The curing agent is used to cure the epoxy resins, which is also sometimes referred to as activator, catalyst, or hardener. For solventborne anticorrosion paints. is the instantaneous rate of heat and After placing the concrete, its exposed surface is first covered with moist hessian or canvas. Doing this requires a concentration of salt of nearly 20%. High reactivity, low temperature cure. Grade 112 USPL offers ultra-low lead (Pb), the lowest lead attainable. Consequently, it will stay in the final film and participate to its chemical and mechanical properties. document.getElementById( "ak_js_1" ).setAttribute( "value", ( new Date() ).getTime() ); Arnette Polymers, LLC Curing of polymers takes place under the action of special reagents (curing agents) or through the interaction of reactive oligomer groups upon exposure to heat, ultraviolet light, or high-energy radiation. Superior chemical resistance. In many cases, the resin is provided as a solution or mixture with a thermally-activated catalyst, which induces crosslinking but only upon heating. From Wikipedia, the free encyclopedia. ultrasonic time of flight, both in through-transmission and pulse-echo modes; natural frequency using impact excitation and, I.Partridge and G.Maistros, Dielectric Cure Monitoring for Process Control, Chapter 17, Vol. Good colour stability, good chemical resistance. Good mechanical, acid and solvent resistance. {\displaystyle \alpha ={\frac {Q}{Q_{T}}}={\frac {\int _{0}^{s}{\dot {Q}}\,dt}{\int _{0}^{s_{f}}{\dot {Q}}\,dt}}} Salicylic acid-free. The global curing agents market was valued at USD 4.26 Billion in 2021 and is anticipated to grow at USD 8 Billion by 2028, growing at a CAGR of 6.78 % during the forecast period 2022-2028. Provides flexibility and thoughness. The precise characterization of new bio-based thermosets is imperative for the correct assessment of their potential as matrix material in fiber-reinforced polymer composites. Some organic resins are cured with heat. Comment: Curing Agents achieve polymerization (crosslinking) at room temperature. [7], To measure the elastic modulus of a system during curing, a rheometer can be used. As a curing agent for fluoroelastomer, ACM or PU, or a modifier for synthetic rubbers, and curing active agent for natural rubber, butyl rubber, isoprene rubber and SBR. Universal aqueous epoxy-polyaminoamide adduct without cosolvent, for concrete and metal coatings. Compounds containing Perkadox 14-40MB-gr have excellent scorch safety, under certain conditions one step mixing is possible. Rubber compounds containing Perkadox 14-40K-pd have excellent scorch safety, under certain conditions one step mixing is possible. Trigonox A-W70 may be used as an initiator for the room temperature cure of promoted unisatmated polyester and vinyl ester resins, and elevated cure of non-promoted resins. Then the reaction continues and the system starts to react more like a solid: the storage modulus increases. . Provides high Tg. In Europe, various regulations have been put in place to control the use of VOCs. Both BLUE FIN 20 and 25 are two component systems, with a 2:1 by volume mix ratio with the hardener. Place an order or get more information about Polyamide Curing Agents: Place an order or get more information about Amidoamine Curing Agents: Place an order or get more information about Mannich Curing Agents: Place an order or get more information about Aliphatic Amine Curing Agents and Accelerators: Place an order or get more information about Cycloaliphatic Amine Curing Agents: Place an order or get more information about Epoxy Reactive Diluents: Place an order or get more information about Waterborne Epoxy & Hardeners: Place an order or get more information about Mercaptans: Place an order or get more information about Solution Epoxy Resins: Place an order or get more information about Voc Exempt Epoxy & Curing Systems: Place an order or get more information about Modified Epoxy and Flexible Systems: Place an order or get more information about Bisphenol F & Novolacs: Place an order or get more information about Amino Resins for Polyurea: Place an order or get more information about Oxazolidines & Aldimines: Based in Richmond, Missouri, our company has a tradition of providing a full range of products and technology to the thermoset polymer industry. In rubber, the curing is also induced by the addition of a crosslinker. Trigonox 29-40B-pd-am is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Benzyl alcohol-free. This grade is used where lower impurities are required and is used in the chemical, tire and rubber, paint and coatings, and all applications For solventfree concrete primers, coatings and adhesives. . , Begin applying the compound as soon as you lay the cement and the surface water disappears. Our curing agents are of various types: unmodified and modified aliphatic or cycloaliphatic amines, epoxy/(cyclo)aliphatic amine adducts, poly(amino)amides and their adducts, Mannich bases and various special curing agents, including waterbornes. Most classical solvents widely used in the coatings, inks, varnishes and adhesives industries are VOCs. Q Volatile Organic Compounds or VOCs are organic chemicals having a low boiling point/high vapour pressure at room temperature. Outstanding flexibility, resistance to humidity and corrosion. Paints and varnishes commonly contain oil drying agents, usually metallic soaps that catalyze cross-linking of the unsaturated drying oils that largely comprise them. High filler loadings. Low exotherm/low reactivity version of Q-RIT 369 for use in thick castings, river tables, decorative applications. a process by which liquid reactive polymers of low molecular weight (oligomers) are irreversibly converted into solid, insoluble, and infusible three-dimensional polymers. 1000 kilograms (Min. RD-0205WH exhibits high reactivity at ambient temperature and forms excellent films when cured with solid or liquid epoxy resins. Curing plays an important role on strength development and durability of concrete. UV-resistance. For construction, paints, adhesives and composites applications. is the heat released up to a certain time Q Typical loading levels are 0.1 to 0.4 phr. ) An additional benefit of RD-0205WH is its inherent pseudoplastic nature, increasing the stability and resistance to settling of zinc rich paints with the zinc dispersed into RD0205WH without water. (a) with a liquid resin (EEW 190), 100 g mix, measured @23C. Triethylenetetramine (TETA). For adhesives, mortars and primers. BLUE FIN FAST is commonly used alone unless ambient temperature is above 30C. , Ascorbates, Erythorbates, Ascorbic Acid. All content on this website, including dictionary, thesaurus, literature, geography, and other reference data is for informational purposes only. Good colour stability, good chemical resistance. Outstanding for low temperature applications. Outstanding flexibility, resistance to humidity and corrosion. For solventfree paints, self-leveling and trowelable floorings, mortars, patching compounds and adhesives. The degree of curing starts from zero (at the beginning of the reaction) and grows until one (the end of the reaction). As nouns the difference between resin and hardener is that resin is a viscous hydrocarbon secretion of many plants, particularly coniferous trees while hardener is one who, or that which, hardens. An approximate order of response by polymer is: NR > NBR > SBR > EPDM > IIR > CR. Order) modified cycloaliphatic polyamine Ancamine 2519 epoxy resin curing agent. Trigonox 29-50PA-pd is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Low exotherm/low reactivity version of Q-RIT 369 for use in thick castings, river tables, decorative applications. For adhesives, solventborne anticorrosion paints and concrete repair. Also used to seal, protect, and dustproof existing concrete, terrazzo, brick, stone, architectural concrete, and . Excellent water and salt spray resistance. 0 High filler loadings. Polyoxypropylenetriamine. You also have the option to opt-out of these cookies. Good substrate impregnation, outstanding adhesion to humid substrates and very good corrosion protection. The curing methodology depends on the resin and the application. Grade 101 USPL offers ultra-low lead (the lowest lead attainable), with medium-high m2/g surface area (SA). Applications in construction, paints, adhesives and composites. Superior resistance tocarbamation / waterspotting. (a) with liquid resin (EEW 190), 100 g mix, measured @23C. Properly curing concrete improves strength, durability, water tightness, and wear resistance. What is the difference between c-chart and u-chart? Dilutable to very low solids for a good impregnation of concrete. Additive for polymers to improve: flame retardant-, thermo-mechanical-, barrier-and/or rheological properties. Can be used on green concrete. Trigonox 101-458-pd-am is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyotefins. O VOC. For use in composite materials (fiber reinforced laminates) or adhesives. For use in composite materials (fiber reinforced laminates) or adhesives. For solventfree paints, floorings, mortars or adhesives. Q Aqueous amine-adduct without cosolvent for metal and concrete coatings. Good flexibility and adhesion, good resistance to corrosion and to chemicals. , can be defined as follows:[9], Trigonox 29-C90 is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Very fast and low viscous. 1>>In UV curable inks and coatings , from the below other then Amines, which one can be used ? Modified cycloaliphatic polyamine. Easy to dose. The inhibition of conjugational transfer of antibiotic resistance plasmid can be used to decrease the spread of antibiotic resistance plasmid in the environment. Can be charged with zinc in the formulation of zinc rich primers. Curing agents have been developed which are a combination of phenalkamine and polyamide and combine most of the positive features of each curing agent while giving a very high biobased mass percentage. The crosslink density increases until the system reaches the end of the chemical reaction.[2]. To clarify the influencing mechanism of superabsorbent polymer (SAP) internal curing agent on the carbonation resistance of cement concrete, accelerated carbonation experiment was conducted to explore the effect of particle size and dosage of SAP on carbonation depth. Terms of Use This grade is widely used in tire and rubber, paint and coatings, in applications requiring an FDA approved substance, and in all other For use in construction, tank linings and composites materials. Even if it is strongly associated with the production of thermosetting polymers, the term "curing" can be used for all the processes where a solid product is obtained from a liquid solution, such as with PVC . Can be used on green concrete. document.getElementById( "ak_js_1" ).setAttribute( "value", ( new Date() ).getTime() ); document.getElementById( "ak_js_2" ).setAttribute( "value", ( new Date() ).getTime() ); We deliver more than just products we deliver solutions and success. Compounds containing Perkadox 14S-fl have excellent scorch safety, under certain conditions one step mixing is possible. G Trigonox C-40B-pd is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. I am currently continuing at SunAgri as an R&D engineer. Very fast and low viscous. Many polymers cannot be properly used without first being cured via the addition of a vulcanizing agent. There are two BLUE FIN systems, BLUE FIN 20 and BLUE FIN 25. "[3] Thus, two broad classes are (i) curing induced by chemical additives (also called curing agents, hardeners) and (ii) curing in the absence of additives. t . Salicylic acid-free. Thus, in order to achieve vitrification in the resin, it is usually necessary to increase the process temperature after gelation. Good heat resistance. s Curing is the process of maintaining satisfactory moisture content and temperature in freshly cast concrete for a definite period of time immediately following placement. Benzyl alcohol-free. Good colour stability, good chemical resistance. Contact H.M. Royal for a technical consult. Superior chemical resistance. A curing agent can be defined as a substance able to participate in the chemical reaction between the oligomer, pre-polymer and polymer, to achieve the polymerization process and provide the final film. In most of the cases it is irreversible and can be either intra or inter-molecular. Cures at up to 70% relative humidity. It can keep the vulcanizate natural and vivid colors. This grade is used where very low impurities are required, and where increased zinc oxide reactivity provides application benefits. The term "curing" is generally used in the processing of plastics, varnishes, adhesives, and sealing compounds. {\displaystyle s} Faster than Q-RIT 163. Your email address will not be published. UV-resistance. Low viscosity, good impregnation, high filler loadings. All Rights Reserved**, Introduction to Biopolymers and Bioplastics, Characterization of Thermosets: 4 Part Video Series, Advanced Thermoset Cure Kinetics: 3 Part Video Series, Guest Post by Jeremy Pasatta, Huntsman Corporation, Epoxy Curing Agents Part 2: Tailoring Properties with Amines, Epoxy Curing Agents Anhydrides, Long Pot Life and Exceptional Properties . Good flexibility and adhesion, good resistance to corrosion and to chemicals. Provides high Tg. Underwater cure. For solvenfree floorings. , , QR-Polymers. t Reduces the quantity of water required. 2,4,6-tris(dimethylaminomethyl)phenol. Trigonox 42-40B-pd is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Trigonox 101-45B-pd is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Applications in construction, paints, composites and castings. Convenient 1:1 mix ratio with bisphenol A epoxy. Removal of water and addition of salt to meat creates a solute-rich environment where osmotic pressure draws water out of microorganisms, slowing down their growth. x It is used both for tubular and autoclave processes. When in acrylic resins a very high degree of transparency of the cured part is required the special grade Perkadox CH-50L is advised. Accredited at 23% biocarbon. SAP is a polymer-based material that can absorb a considerable quantity of water from the surroundings, resulting in the swelling of the polymer matrix and thus retain water without dissolving. C08G59/40 Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. In consideration of ongoing demand and usability of SAP, this . This ratio provides the mechanical properties that are desirable and optimum biocompatibility. 5, Encyclopaedia of Composite Materials (2001), Elsevier Science, London, page 413. Low temperature/high humidity cure. Curing transforms the polymer into a more durable, resilient product. Composite cure ovens are used for curing, annealing, drying and hardening synthetic and composite materials. Long pot-life, flexibility, good impregnation. Not sure which type of rubber to substrate adhesive is necessary for your compound or product? This website uses cookies to improve your experience. Flavoring agents flavor improvement, bacterial inhibition, color improvement, antioxidant function. Outstanding adhesion to concrete. High crosslinking rate, good chemical resistance, fast drying. Several versions of dielectric sensors are available commercially. In terms of processability of the resin this marks an important stage: before gelation the system is relatively mobile, after it the mobility is very limited, the micro-structure of the resin and the composite material is fixed and severe diffusion limitations to further cure are created. Q Amines are called monoamine, diamine, tri-amine, or polyamine according to the number of amines in one molecule. Polyetheramine, Mw 400. Good flexibility and adhesion, good substrate wetting, good temperature resistance. Trigonox 17-40B-pd is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins. Faster than Q-RIT 163. The process is not induced by additives. General purpose high-solids curing agent for heavy duty coatings. m Grade 112 USP replaces Grades Zinc Oxide LLC USP10, ZOCO 112 USP, and KADOX USP-3. {\displaystyle \alpha } n These cookies will be stored in your browser only with your consent. UV resistance. A simple way to monitor the change in viscosity, and thus, the extent of the reaction, in a curing process is to measure the variation of the elastic modulus. For solventfree concrete coatings, concrete repair and high-solids primers. A concrete curing agent forms a membrane over the top of the concrete slab while it cures. = Good mechanical and chemical resistance. The standard mixing ratio for PDMS is 10-parts base elastomer and 1-part curing agent. Good mechanical, acid and solvent resistance. Cures at up to 80% relative humidity. For construction, paints, adhesives and composites applications. Excellent bonding to wood, metal and plastic. Low molecular weight polyetheramine. Salicylic acid-free. Slow version of Q-RIT 1071. Good impregnation. Good resistance tocarbamation / waterspotting and to chemicals. Aqueous amine-adduct without cosolvent for general industrial coatings, floorings, epoxy-modified concrete, grouts. Amine-adduct, 70% solids in propylene glycol n-butyl ether. The degree of crosslinking determines the rigidity and durability, as well as other properties of the material.[5]. The materials are often bagged and put under a vacuum while being cured. Out of these, the cookies that are categorized as necessary are stored on your browser as they are essential for the working of basic functionalities of the website. Excellent waterspot resistance. But opting out of some of these cookies may affect your browsing experience. For waterborne dispersions. 1000 kilograms (Min . Even though these terms are used indiscriminately, they are different. Crosslinking boosts the thermal stability and mechanical properties of the polymer. Product Line Cards. Best used to cure hams, bacon and smaller cuts of meat, dry curing involves applying the cure mix directly on the meat. For adhesives and solventborne or solventfree anticorrosion paints. For use in composite materials (fiber reinforced laminates) or adhesives. Crosslinking is a process of associating polymers through a chemical bond. For solvenfree self-leveling floorings, and paints. {\displaystyle \alpha ={\frac {G'(t)-G'_{min}}{G'_{max}-G'_{min}}}} The first type of curing agents includes active hydrogen-containing compounds and their derivatives. For solventfree and solventborne curing agents, see below. If the reactions occurring during crosslinking are exothermic, the crosslinking rate can be related to the heat released during the process. It is capable of monitoring phase separation in complex resin blends curing also within a fibrous perform. For special curing agents requests, please contact us. Your email address will not be published. G Good colour stability, good chemical resistance. = $3.00 / kilogram. This product is also available with around up to 0.1% processing aid/surface treatment (grade 102T) for some rubber mixers. Curing refers to the technological process involving the addition of salt and nitrates and/or nitrites to different types of raw materials to produce the so-called cured food products. Therefore, the mechanical properties of diglycidyl ether of bisphenol a (DGEBA) cured with either l-arginine, l-citrulline, &gamma;-aminobutyric acid, l-glutamine, l-tryptophan, or l-tyrosine were investigated to determine the potential of amino acids . use of water-soluble polymers as self-curing agents in concrete has found several applications recently [1]. An intermediate case involves a mixture of resin and additives that requires external stimulus (light, heat, radiation) to induce curing. Adhesion on humid concrete. The B side, also known as the hardener, is the epoxy curing agent; the curing agent is responsible for reacting with the epoxy groups contained in the epoxy resin A side. Fast curing. Epoxy resin systems consist of two parts, an A and a B side. Excellent waterspot resistance. For waterborne curing agents click here. Diethylenetriamine (DETA). Click here to get more information on Curing Agent. Deeks Division: 4748 Lewis Road Stone Mountain, GA 30083 P | 770-938-3100 Therefore, the mechanical properties of diglycidyl ether of bisphenol a (DGEBA) cured with l-arginine were investigated to determine whether the bio-based thermoset possesses the required mechanical properties for . In addition, blending vessels range in size from 10,500 gallons to 1,000 gallons. P.Ciriscioli and G.Springer, Smart Autoclave cure in Composites, (1991), Technomic Publishing, Lancaster, PA. Good substrate impregnation, outstanding adhesion to concrete and to humid substrates. general methods of curing characterised by the curing agents used; C08G59/62 Alcohols or phenols; C08G59/625 Hydroxyacids For special curing agents requests, please contact us. Good heat resistance. Excellent flexibility, good humidity and corrosion resistance. , when the reaction finishes. The variation of G' and G" in time can indicate the extent of the curing reaction. Economical hardener. Curing is a chemical process employed in polymer chemistry and process engineering that produces the toughening or hardening of a polymer material by cross-linking of polymer chains. UV-resistance. Applications in construction, paints, adhesives and composites. For use in construction, tank linings and composites materials. When carbon black is used as the main filler, 2-3 phr should be used; when mineral filler is used, the dose should be 3-4 phr. The right curing agent depends on the base polymer, the processing conditions, and the physical and service requirements of the finished compound. {\displaystyle {\dot {Q}}} Trigonox 117 can be used to crosslink elastomers at intermediate temperatures, a typical crosslink temperature is 150 C. Trigonox 117 is recommended for highly demanding applications e.g. To measure the heat flow differential scanning calorimetry can be used. Today, the civil engineering and coatings industries are without any doubt convinced of the advantages of using waterborne epoxy systems: these systems are environmentfriendly, they offer enhanced work comfort (less smell) and reduced toxicity for the applicators working in closed areas. For use in adhesives, putties, mortars and impregnation compounds. Faster than Q-RIT 305. CTPI is used as an inhibitor of premature vulcanization of synthetic and natural rubbers, providing the rubber compounder with a better means of controlling scorch safety. What is the shape of C Indologenes bacteria? Main Advantages of Polymercaptan Curing Agents. What is PDMS curing agent? Regards, Other Curing Agents (Arizidine, Mercapto compounds), Select Optimum Amine Curing Agent for Epoxy Resin as per Your Need, Material Selector: Check out the complete list of silane coupling agents here , various types of polyisocyanates available on the market, Selecting the right curing agent technology, Sometimes the polymerization cannot starts without a curing agent, Curing agent reacts and participates in the final film build and give some specific properties, allow the 3D network, The curing agent stays in the polymer build after the reaction, Specific curing agents may bring some extra properties to the system through the proper build of a 3D network with the binder, Influence the curing time, even under low temperatures, Ability to accelerate other amines and polyamides (that is why they are commercially available with and without amine accelerator), Manipulate the finished coating's characteristics, The chemical nature and functionality of the resin system.

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